Enhancement of structural rearrangement in glassy systems under shear flow

We extend the analysis of the mean field schematic model recently introduced for the description of glass forming liquids to the case of a supercooled fluid subjected to a shear flow of rate $\gamma$. After quenching the system to a low temperature $T$, a slow glassy regime is observed before stationarity is achieved at the characteristic time $\tau_g$. $\tau_g$ is of the order of the usual equilibration time without shear $\tau_g^o$ for weak shear, $\gamma \tau_g ^o1$, local rearrangement of dense regions is instead enhanced by the flow, and $\tau_g \simeq 1/(T\gamma)$.Comment: 8 pages, 3 figures, changed content Pacs{64}{70.Pf}{Glass transitions} Pacs{05}{70.Ln}{Non-equilibrium thermodynamics, irreversible processes} Pacs{83}{50.Ax}{Steady shear flows

Evidence of aging in mean-field spin glass models

We study numerically the out of equilibrium dynamics of the hypercubic cell spin glass in high dimensionalities. We obtain evidence of aging effects qualitatively similar both to experiments and to simulations of low dimensional models. This suggests that the Sherrington-Kirkpatrick model as well as other mean-field finite connectivity lattices can be used to study these effects analytically.Comment: 13 pages + 5 figures (upon request

Fluctuation theorems and atypical trajectories

In this work, we have studied simple models that can be solved analytically to illustrate various fluctuation theorems. These fluctuation theorems provide symmetries individually to the distributions of physical quantities like the classical work ($W_c$), thermodynamic work ($W$), total entropy ($\Delta s_{tot}$) and dissipated heat ($Q$), when the system is driven arbitrarily out of equilibrium. All these quantities can be defined for individual trajectories. We have studied the number of trajectories which exhibit behaviour unexpected at the macroscopic level. As the time of observation increases, the fraction of such atypical trajectories decreases, as expected at macroscale. Nature of distributions for the thermodynamic work and the entropy production in nonlinear models may exhibit peak (most probable value) in the atypical regime without violating the expected average behaviour. However, dissipated heat and classical work exhibit peak in the regime of typical behaviour only.Comment: 14 pages, 7 figure

Fluctuation theorem for non-equilibrium relaxational systems driven by external forces

We discuss an extension of the fluctuation theorem to stochastic models that, in the limit of zero external drive, are not able to equilibrate with their environment, extending results presented by Sellitto (cond-mat/9809186). We show that if the entropy production rate is suitably defined, its probability distribution function verifies the Fluctuation Relation with the ambient temperature replaced by a (frequency-dependent) effective temperature. We derive modified Green-Kubo relations. We illustrate these results with the simple example of an oscillator coupled to a nonequilibrium bath driven by an external force. We discuss the relevance of our results for driven glasses and the diffusion of Brownian particles in out of equilibrium media and propose a concrete experimental strategy to measure the low frequency value of the effective temperature using the fluctuations of the work done by an ac conservative field. We compare our results to related ones that appeared in the literature recently.Comment: 39 pages, 6 figure

Dynamical transition of glasses: from exact to approximate

We introduce a family of glassy models having a parameter, playing the role of an interaction range, that may be varied continuously to go from a system of particles in d dimensions to a mean-field version of it. The mean-field limit is exactly described by equations conceptually close, but different from, the Mode-Coupling equations. We obtain these by a dynamic virial construction. Quite surprisingly we observe that in three dimensions, the mean-field behavior is closely followed for ranges as small as one interparticle distance, and still qualitatively for smaller distances. For the original particle model, we expect the present mean-field theory to become, unlike the Mode-Coupling equations, an increasingly good approximation at higher dimensions.Comment: 44 pages, 19 figure

A first principle computation of the thermodynamics of glasses

We propose a first principle computation of the equilibrium thermodynamics of simple fragile glasses starting from the two body interatomic potential. A replica formulation translates this problem into that of a gas of interacting molecules, each molecule being built of m atoms, and having a gyration radius (related to the cage size) which vanishes at zero temperature. We use a small cage expansion, valid at low temperatures, which allows to compute the cage size, the specific heat (which follows the Dulong and Petit law), and the configurational entropy.Comment: Latex, 40 pages, 9 figures, corrected misprints, improved presentatio